There's lots of great VR stuff. My personal collection includes GT Sport, wipEout Omega, Hustle Kings, Bound, Gunjack, R.I.G.S., Starblood Arena, Rush of Blood, PlayStation VR Worlds and Polybius. All of those i can recommend to you.
@blackwiggle: I played the demo version of Moss, which i liked as well. If you like to score goals with your head, Headmaster is a great experience. And the demo of Thumper was convincing (bug ship)